От химических димеров порфиринов к сложным мультикомпонентным наноансамблям: некоторые редкие явления и релаксационные процессы

  • Э. И. Зенькевич
  • Д. Р.Т. Цан
  • К. фон Борцисковски
Ключевые слова: Самосборка, порфирины, химические димеры, триады, перенос энергии, перенос заряда, неоднородное уширение энергетических уровней, дистанционный фотоиндуцированный перенос электрона по механизму суперобмена, коллоидные полупроводниковые квантовые точки.

Аннотация

В результате многолетнего и плодотворного сотрудничества с профессором Г.В. Пономаревым и доктором А.М. Шульгой и благодаря их высокому профессионализму на основе подхода «снизу-вверх» были получены высокорганизованные мультипорфириновые комплексы различной морфологии, а также наноансамбли на основе полупроводниковых квантовых точек и порфиринов. С использованием стационарной и время-разрешенной спектроскопии в комбинации с методами высокого спектрального разрешения были обнаружены и исследованы специфические и/или редкие процессы релаксации энергии возбуждения (выжигание спектральных провалов, Т-Т перенос в димерах, фотоиндуцированный перенос электрона при низких температурах, дистанционный перенос заряда по механизму суперобмена и т.д.).

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Опубликован
2022-06-25
Раздел
Порфирины